Shin-Etsu Silicone Selection Guide for Cosmetics

W/O Applications

Emulsifying silicone gels and silicone emulsifiers can be used as emulsifiers in W/O emulsions.
Emulsifying silicone gels (KSG Series) is a swollen form of a three-dimensional crosslinked structure, where silicone is crosslinked with hydrophilic groups. It strengthens the interface of emulsion particles and maintains stability. It is also suitable for preparing high internal phase W/O emulsions.
Silicone emulsifiers (KF Series) feature silicone chains with either straight-chain or branched structures, enabling control over emulsion particle size and making them suitable for preparing finer emulsions. A wide variety of hydrophobic and hydrophilic groups are available, allowing selection based on application and desired texture.

Molecular Image of emulsifying silicone gels (KSG Series)

A three-dimensional crosslinked structure formed by crosslinking silicone with hydrophilic groups.
It features an intertwined molecular structure and swells in various silicone fluids.

Product Lineup and Molecular Structure Models of Emulsifying Silicone Gels

standard type alkyl branched type silicone / alkyl branched type
polyether modified polyglycerin modified Base Oil polyether modified polyglycerin modified Base Oil polyether modified polyglycerin modified Base Oil
KSG-210 KSG-710 KF-96A-6cs Dimethicone KSG-310 KSG-810 Mineral Oil KSG-320Z KSG-820Z Isododecane
KSG-240  

KF-995

Cyclopentasiloxane

KSG-320 KSG-820 Isododecane KSG-350Z KSG-850Z

KF-995

Cyclopentasiloxane

KSG-270  

KF-56A

Phenyl-modified silicone

KSG-330 KSG-830 Triethylhexanoin KSG-360Z  

KF-96A-6cs

Dimethicone

      KSG-340 KSG-840 Squalane KSG-380Z  

KF-96L-2cs

Dimethicone

Molecular Structure Model of Cross-linked Material
Features
Useful in formulations primarily containing silicone fluids Useful in formulations primarily composed of ester oils and hydrocarbon oils Useful in formulations that combine silicone fluids, ester oil, hydrocarbon oil, etc.

Using emulsifying silicone gels enables the formation of large-particle-size W/O emulsions. Since the crosslinked material strengthens the interface of the emulsion particles, it is possible to prepare W/O creams containing a very large amount of aqueous phase in the internal phase. Furthermore, because the crosslinked material swells in the silicone fluids and imparts structural viscosity, stable W/O cosmetic formulations can be obtained.
The hydrophobic portion comes in three types: a standard type composed solely of silicone chains, a type with alkyl chains unrelated to crosslinking, and a type with two types of branched chains (silicone and alkyl). Each swells in compatible silicone fluids.
The hydrophilic components come in two types: polyether and polyglycerin modified. Being three-dimensional crosslinked compounds, they provide a non-sticky feel. In particular, polyglycerin modified silicone offers high moisture retention, delivering a soft and moisturized texture.

Product Lineup and Molecular Structure Models of Silicone Emulsifiers

Type Product molecular model
linear type (Surfactant/Dispersant) polyether modified
Useful for emulsified formulations primarily containing silicone fluids
KF-6015 KF-6017 KF-6017P
Polyethers and Alkyl Copolymerization
Useful for emulsified formulations primarily composed of ester oils and hydrocarbon oils
KF-6048
Branching Type (Activator/Dispersant) polyether modified
Useful for emulsified formulations primarily containing silicone fluids
KF-6028 KF-6028P
polyglycerin modified
Useful for emulsified formulations primarily containing silicone fluids
KF-6104
Polyethers and Alkyl Copolymerization
Useful for emulsified formulations that combine silicone fluids, hydrocarbon oil, etc.
KF-6038
Polygyceryl Alkyl Copolymer
Useful for emulsified formulations that combine silicone fluids, hydrocarbons, etc.
KF-6105

Silicone emulsifiers with linear or branched hydrocarbon groups can control emulsion particle size and are suitable for preparing finer emulsions.
Our linear type lineup includes products with various HLB values; those with low HLB values are useful as W/O emulsifiers.
We also offer products with alkyl chains attached to the silicone backbone (KF-6048).
Silicone branched types include those with only silicone branches (KF-6028, 6104) and those with two types of branches: silicone and alkyl (KF-6038, 6105).
The optimal choice can be made based on the compatibility between the silicone fluids used and each surfactant.
There are two types of hydrophilic groups: polyether and polyglycerin.Polyether-modified silicone enables the preparation of finer emulsions,Polyglycerin modified silicone provides high water retention and a soft, moisturized feel.

  • Product Category

  • Ingredient Function

KF-6028

KF-6028

A branched silicone chain polyether-modified silicone surfactant that can be used as a W/Si emulsifier. It has excellent solubility in oil and can be used to create products with characteristics such as emulsion viscosity and stability. HLB: 4.0

KF-6017

KF-6017

A polyether-modified silicone surfactant that can be used as a W/Si emulsifier. HLB: 4.5

KF-6028P

KF-6028P

A branched silicone chain polyether-modified silicone surfactant that can be used as a W/Si emulsifier. It has excellent solubility in oil and can be used to create products with characteristics such as emulsion viscosity and stability. HLB: 4.0

KF-6017P

KF-6017P

A polyether-modified silicone surfactant that can be used as a W/Si emulsifier. HLB: 4.5

KF-6048

KF-6048

A branched alkyl chain polyether-modified silicone surfactant that can be used as a W/O emulsifier. It exhibits excellent solubility in a wide range of organic oils containing OMC, enabling the production of products with distinctive characteristics such as viscosity and stability of emulsions. HLB: 3.5

KF-6015

KF-6015

A polyether-modified silicone surfactant that can be used as a W/Si emulsifier. HLB: 4.5

KF-6038

KF-6038

Silicone alkyl chain co-variable polyether modified silicone surfactant. Can be used as an emulsifier for W/Si and W/O systems. Exhibits excellent solubility in both silicone fluid and fatty oils, enabling the production of products characterized by emulsion viscosity and stability. HLB: 3.0

KF-6180

KF-6180

W/O silicone emulsifier with high emulsification performance for plant oils and UV absorbers.

KF-6106

KF-6106

A polyglycerol-modified silicone surfactant with branched silicone chains. It has high adsorbability to pigment surfaces and can be used as an excellent dispersant for pigments in silicone. HLB: Low

KF-6104

KF-6104

A polygycerol-modified silicone surfactant with branched silicone chains. Can be used as a W/Si emulsifier. Excellent moisture retention, and emulsions containing this product are easily absorbed by the skin, leaving it feeling very soft and moist. HLB: Low

KF-6105

KF-6105

Silicone alkyl chain comonomer modified polyglycerin silicone surfactant. Can be used as a W/Si and W/O emulsifier. It has excellent solubility in both silicone fluid and oils and fats, enabling the creation of products characterized by their viscosity and stability after emulsification. It has excellent moisture retention properties, and emulsions containing this product are easily absorbed by the skin, giving it a very soft and moist feel. HLB: Low

KSG-850Z

KSG-850Z

  • This emulsifier has high water retention and is easily absorbed by the skin, giving it a soft, moist feel.
  • It can be used to create unique W/Si and W/O creams.

KSG-320

KSG-320

A smooth-feeling emulsifier that can be used to create unique W/Si and W/O creams.

KSG-790

KSG-790

  • Silicone gel active agent that enables the design of W/O emulsion formulations with high stability in a wide range of oil agents.

KSG-270

KSG-270

  • This emulsifier has a smooth texture and can be used to create unique W/Si and W/O creams.
    The base oil, phenyl-modified silicone, is highly compatible with silicone fluid, hydrocarbon oil, UV absorbers, and other ingredients, allowing for a wide range of oil combinations.

KSG-340

KSG-340

A smooth-feeling emulsifier that can be used to create unique W/Si and W/O creams.

KSG-350Z

KSG-350Z

A smooth-feeling emulsifier that can be used to create unique W/Si and W/O creams.

KSG-810

KSG-810

  • This emulsifier has high water retention and is easily absorbed by the skin, giving it a soft, moist feel. It can be used to create unique W/Si and W/O creams.

KSG-830

KSG-830

  • This emulsifier has high water retention and is easily absorbed by the skin, giving it a soft, moist feel..
  • It can be used to create unique W/Si and W/O creams.

KSG-360Z

KSG-360Z

A smooth-feeling emulsifier that can be used to create unique W/Si and W/O creams.

KSG-310

KSG-310

A smooth-feeling emulsifier that can be used to create unique W/Si and W/O creams.

KSG-330

KSG-330

A smooth-feeling emulsifier that can be used to create unique W/Si and W/O creams.

KSG-840

KSG-840

  • This emulsifier has high water retention and is easily absorbed by the skin, giving it a soft, moist feel.
  • It can be used to create unique W/Si and W/O creams.

KSG-240

KSG-240

A smooth-feeling emulsifier that can be used to create unique W/Si and W/O creams.

KSG-710

KSG-710

  • This emulsifier has high water retention and is easily absorbed by the skin, giving it a soft, moist feel.
  • It can be used to create unique W/Si and W/O creams.

KSG-210

KSG-210

A smooth-feeling emulsifier that can be used to create unique W/Si and W/O creams.

KSG-820Z

KSG-820Z

  • This emulsifier has high water retention and is easily absorbed by the skin, giving it a soft, moist feel.
  • It can be used to create unique W/Si and W/O creams.

KSG-820

KSG-820

  • This emulsifier has high water retention and is easily absorbed by the skin, giving it a soft, moist feel..
  • It can be used to create unique W/Si and W/O creams.

KSG-380Z

KSG-380Z

A smooth-feeling emulsifier that can be used to create unique W/Si and W/O creams.

KSG-320Z

KSG-320Z

A smooth-feeling emulsifier that can be used to create unique W/Si and W/O creams.