Shin-Etsu Silicone Selection Guide

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How to increase the solubility of silane coupling agent in water and improve the storage stability of the solution?

The alkoxysilyl groups of silane coupling agents become silanol groups when dissolved in water.
This silanol group is unstable and undergoes condensation reactions over time. This results in the formation of siloxane bonds, which eventually lead to gelation.
In general, silanol groups are unstable in aqueous solution, but are relatively stable in a mildly acidic.
Also, aminosilanes are very stable in aqueous solutions due to their interaction with amino groups. To improve the storage stability of the solution, the pH of the solution can be adjusted, alcohol can be used in combination with the solution, and the solution can be stored below room temperature.

Solubility and Stability at Optimum pH

Product name Solubility (pH of aqueous solution) Storage stability
KBM-1003 Soluble(3.9) Within 10 days
KBE-1003 Soluble(3.9) Within 10 days
KBM-303 Soluble(4.0) Within 30 days
KBM-403 Very soluble(5.3) Within 30 days
KBE-402 Soluble(4.0) Within 10 days
KBE-403 Soluble(4.0) Within 10 days
KBM-1403 Insoluble
KBM-502 Soluble(4.0) Within 1 day
KBM-503 Soluble(4.2) Within 1 day
KBM-5103 Soluble(4.2) Within 3 days
KBM-602 Very soluble(10.0) Within 30 days
KBM-603 Very soluble(10.0) Within 30 days
KBM-903 Very soluble(10.0) Within 30 days
KBE-903 Very soluble(10.0) Within 30 days
KBM-573 Soluble(4.0) Within 1 day
KBM-803 Soluble(4.0) Within 1 day

*Solubility
Very soluble: 1% silane aqueous solution can be prepared without adjusting the pH of the aqueous solution.
Soluble: 1% silane aqueous solution can be prepared by adjusting the pH of the aqueous solution.
Insoluble: Aqueous silane solution cannot be prepared.
*Storage stability is only a guideline and may vary depending on usage conditions and purposes.