Shin-Etsu Silicone Selection Guide

X-12-1333A

   
Required Performance Heat ResistanceAdhesion
Features and Applications Surface ModificationFiller Surface TreatmentCoating Agent
  • Silane coupling agent with cyclization polymerization properties
  • Superior thermal degradability and adhesiveness compared to KBM-503 and KBM-5103
  • Silane coupling agent with acrylic groups as organic functional groups
  • This product is used for processing silica.

Product Information

Applicable solvent type Organic solvent type, Water type
Applicable resin Acrylic, Polycarbonate, Urethane, ABS, EPDM, EPM, Diallyl phthalate, Unsaturated polyester, Polyethylene, Polypropylene
Solvent type Solvent-free
Usage Additive, Primer, Filler treatment
Organic functional groups Acrylic group
Chemical name 2-(Allyloxymethyl)acrylic acid (trimethoxysilyl) propyl
CAS No. 2649015-00-7
Flash Point (°C) 182
Minimum covering area m2/g 256
SP value 8.84
Molecular weight 304.4
Specific gravity 1.06
Refractive index 1.444
Boiling point (°C) 150℃/0.80kPa
Number of alkoxy groups 3
Methoxy/ethoxy group Methoxy group
Optimum pH 3-4
Water solubility
UN Number UN3082
Packaging 1kg

(Not specified values)

Forms THF Ring by Cyclization Polymerization

Heat Resistance Test Data

Thermal Weight Loss of Homopolymer


Thermal Weight Loss of MMA Copolymer


Aqueous Solution Stability

It is stable in aqueous solution and maintains its transparency.
X-12-1333A KBM-503
Appearance of 0.5% silane solution
Formulation

Silane 0.5wt%

pH 3.6 Acetic acid solution 99.5wt%.

Application to Primers

【Primer】 Add 1 wt% silane to methanol:water = 50:50 (stirred for 1 hour) 【Top paint】 Resin = LUXYDIR 17-813 (urethane acrylate manufactured by DIC Corporation) Photoinitiator = Omnirad184 (manufactured by IGM Resins) Resin : Photoinitiator = 100 : 2.4 【Application】 ①Flow coat primer on glass substrate, 80°C x 5min. drying
②Top coating is applied with a bar coater (20 μm film thickness), dried at 80°C x 10 min. and UV irradiated (600 mJ).
Item / Silane Coupling Agents Blank X-12-1333A KBM-503 KBM-5103
Appearance Colorless transparent Colorless transparent Colorless transparent Colorless transparent
Pencil hardness 750g load 5H 6H 5H 5H
Adhesion (Cross cut adhesion test) 25/25 25/25 25/25 25/25
After immersion in hot water Adhesion (Cross cut adhesion test) 80℃×2h 0/25 25/25 0/25 0/25

(Not specified values)

Evaluation as an Adhesion Aid (UV-curable Silicone)

【Combination】 UV-curable silicone polymer 100 parts Adhesion aid silane coupling agent 3 parts Photoinitiator 1 part 【Curing conditions】 Under N2 atmosphere UV-LED irradiation(365nm, 100mW/cm2, 80sec)
Item / Silane Coupling Agents Blank X-12-1333A KBM-5103
Hardness Durometer A * 45 43 42
Hardness Durometer A * (MPa) * 5.2 4.9 4.1
Elongation at break % * 110 100 90
Tensile lap-shear strength (glass) (MPa) t=230 μm 1.7 4.4 3.9

*2mm sheet physical properties

(Not specified values)

Product Inquiry

X-12-1333A

Inquiry Form

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Related Product List

Product Name Organic Fucntional Group Product Category Applicable Solvent System For Polyethylene For Polypropylene For Polystyrene For Acrylic For PVC For Polycarbonate For Nylon For Urethane For PBT・PET For ABS For Melamine For Phenol For Epoxy For Polyimide
X-12-1126 Quaternary Ammonium Salt Antibacterial Silane Organic Solvent, Water System + + + + + + + + + + +
KBM-9418-40 Quaternary Ammonium Salt Antibacterial Silane Organic Solvent, Water System + + + + + + + + + + +
POLON-V8 Quaternary Ammonium Salt Antibacterial Silane Organic Solvent, Water System + + + + + + + + + + +
X-12-1139 Quaternary Ammonium Salt Antibacterial Silane Organic Solvent, Water System + + + + + + + + + + +
X-12-1048 Acrylic Multi Functional Group Type (Organic Chain Type) Organic Solvent, Water System + + + + + + ++ +
X-12-1050 Acrylic Multi Functional Group Type (Organic Chain Type) Organic Solvent, Water System + + + + + + ++ +
KBM-5103 Acrylic Organic Solvent, Water System + + + + + + ++ +
KBP-64 Amino VOC Free Type Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
KBP-90 Amino VOC Free Type Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
KBE-9103P Amino Protected Functional Group Type Organic Solvent + + ++ ++ ++ + ++ + + + + ++ ++ +
X-12-1172ES Amino Protected Functional Group Type Organic Solvent + + ++ ++ ++ + ++ + + + + ++ ++ +
KBE-903 Amino Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
X-12-972F Amino Multi Functional Group Type (Organic Chain Type) Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
KBM-6803 Amino Long Chain Spacer Type Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
KBM-573 Amino Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
KBM-575 Amino Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
KBM-602 Amino Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
KBM-603 Amino Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
KBM-903 Amino Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
KBM-6103 Amino Short Chain Silane Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
X-12-5263HP Amino Multi Hydrolytic Group Type Organic Solvent, Water System + + ++ ++ ++ + ++ + + + + ++ ++ +
KBM-3086 Multi Hydrolytic Group Type Organic Solvent, Water System + + + + + + + + + + + + + +
KBM-9659 Isocyanurate Multi Hydrolytic Group Type Organic Solvent, Water System + + + + + + + + + + + + + +
KBE-9007N Isocyanate Organic Solvent + + ++ + + + + + ++
X-12-1159L Isocyanate Multi Functional Group Type (Organic Chain Type) Organic Solvent + + ++ + + + + + ++
X-12-1195 Blocked Type Organic Solvent, Water System + ++ ++ + + + + + ++
X-12-1293 Blocked Type Organic Solvent, Water System + ++ ++ + + + + + ++
X-12-1308ES Blocked Type Organic Solvent, Water System + ++ ++ + + + + + ++
KBE-585A Ureido Organic Solvent, Water System ++ ++ + + +
KBM-585 Ureido Organic Solvent, Water System ++ ++ + + +
KBE-402 Epoxy Organic Solvent, Water System + + + + + + + + + + + + + +
KBE-403 Epoxy Organic Solvent, Water System + + + + + + + + + + + + + +
KBM-303 Epoxy Organic Solvent, Water System + + + + + + + + + + + + + +
KBM-402 Epoxy Organic Solvent, Water System + + + + + + + + + + + + + +
KBM-403 Epoxy Organic Solvent, Water System + + + + + + + + + + + + + +
X-12-981S Epoxy Multi Functional Group Type (Organic Chain Type) Organic Solvent, Water System + + + + + + + + + + + + + +
X-12-984S Epoxy Multi Functional Group Type (Organic Chain Type) Organic Solvent, Water System + + + + + + + + + + + + + +
KBM-4803 Epoxy Long Chain Spacer Type Organic Solvent, Water System + + + + + + + + + + + + + +
X-12-1135 Carboxy VOC Free Type Organic Solvent, Water System + + + + + + + + + + +
X-12-1116 Chelate Functional Type Organic Solvent, Water System + + + + + + + + + + +
X-12-989MS Chelate Functional Type Organic Solvent, Water System + + + + + + + + + + +
KBM-1403 Styryl Polymerizable Type Organic Solvent + +
KBE-1003 Vinyl Organic Solvent, Water System ++ ++
X-12-1290 Vinyl Polymerizable Type Organic Solvent, Water System ++ ++
KBM-1003 Vinyl Organic Solvent, Water System ++ ++
KBM-1083 Vinyl Long Chain Spacer Type Organic Solvent, Water System ++ ++
X-12-1214A Benzotriazole Type Organic Solvent, Water System + + + ++ ++ + + + + + ++
KBE-502 Methacrylic Organic Solvent, Water System ++ ++ ++ + + + ++
KBE-503 Methacrylic Organic Solvent, Water System ++ ++ ++ + + + ++
KBM-502 Methacrylic Organic Solvent, Water System ++ ++ ++ + + + ++
KBM-503 Methacrylic Organic Solvent, Water System ++ ++ ++ + + + ++
KBM-5803 Methacrylic Long Chain Spacer Type Organic Solvent, Water System ++ ++ ++ + + + ++
X-12-1303MS Methacrylic Short Chain Silane Organic Solvent, Water System ++ ++ ++ + + + ++
X-12-1056ES Mercapto Protected Functional Group Type Organic Solvent ++ ++ ++ + + + ++
X-12-1154 Mercapto Multi Functional Group Type (Organic Chain Type) Organic Solvent, Water System ++ ++ ++ + + + ++
KBM-802 Mercapto Organic Solvent, Water System ++ ++ ++ + + + ++
KBM-803 Mercapto Organic Solvent, Water System ++ ++ ++ + + + ++
X-12-1307 Mercapto Short Chain Silane Organic Solvent, Water System ++ ++ ++ + + + ++
X-12-1267B Modified Type Organic Solvent + + + + + + + + + + + + + +
X-12-1267B-ES Modified Type Organic Solvent + + + + + + + + + + + + + +
X-12-967C Acid Anhydride Protected Functional Group Type Organic Solvent, Water System + + + ++ ++ + + + + + ++
X-12-1287A Modified Type Organic Solvent + + + + + + ++ ++ + + + + + ++
X-88-475 Amino Organic Solvent, Water System + + ++ ++ ++ + ++ ++ + + + ++ ++ +
X-12-1333A Acrylic Polymerizable Type Organic Solvent, Water System + + + + + + ++ +